However beautiful the strategy, you should occasionally look at the results.
— Winston Churchill 

Recommended Reading

Web Development & Design

 HTML for the World Wide Web with XHTML and CSS - Elizabeth Castro
HTML for the World Wide Web with XHTML and CSS - Elizabeth Castro
DHTML and CSS for the World Wide Web - Jason Cranford Teague
DHTML and CSS for the World Wide Web - Jason Cranford Teague
 

I highly recommend the Visual QuickStart Guides as an entry guide into just about anything... I own about 10 QuickStart Guides on various topics, and they offer a good introduction into just about any subject or software. They are easy to read, and relatively inexpensive.

 Eric Meyer on CSS
Eric Meyer on CSS
More Eric Meyer on CSS
More Eric Meyer on CSS
 

 Cascading Style Sheets: The Definitive Guide by Eric A. Meyer
Cascading Style Sheets: The Definitive Guide
Designing CSS Web Pages by Christopher Schmitt & Eric A. Meyer
Designing CSS Web Pages
 

I think that the very best way to get into CSS is to jump in and hang on—it's a lot different than designing with tables, and I don't think you'll find all the answers in any one book. Yet, I find Eric Meyer's books very useful. His was one of the first books purchased when I started investigating CSS, and 3-4 years later still find myself peeking into it. I was fortunate to attend his seminar at the UEI User Interface Conference

 Web Designer's Reference : An Integrated Approach to Web Design with XHTML and CSS - Craig Grannell
Web Designer's Reference : An Integrated Approach to Web Design with XHTML and CSS - Craig Grannell
The Zen of CSS Design - Dave Shea, Molly E. Holzschlag
The Zen of CSS Design - Dave Shea, Molly E. Holzschlag
 

Accessibility

 Constructing Accessible Websites - Jim Thatcher
Constructing Accessible Websites - Jim Thatcher
Computer Resources for People With Disabilities: A Guide to Assistive Technologies, Tools, and Resources for People of All Ages - Stephen Hawking
Computer Resources for People With Disabilities: A Guide to Assistive Technologies, Tools, and Resources for People of All Ages - Stephen Hawking
 

The first book,"Constructing Accessible Websites" offers a really good overview of accessibility—what to do, how to do it, why it matters, as well as a bit on laws concerning accessibility. The second book is a reference for people with disabilities & a guide to available technologies and the various resources as well as those found in the marketplace. I thought it was interesting to read them both.

Design & Usability

 Designing Web Usability : The Practice of Simplicity - Jakob Nielsen
Designing Web Usability : The Practice of Simplicity - Jakob Nielsen
Web Site Usability - Mark Pearrow
Web Site Usability - Mark Pearrow
 

 Handbook of Usability Testing - Jeffrey Rubin
Handbook of Usability Testing - Jeffrey Rubin
 

These 3 books are a little old (1998-2000), but I still find them useful. Jakob Nielsen's book is sort of "the gospel according to Jakob," but it is a good overview and introduction into usability and his work is highly regarded in the industry. Although I think he's a bit of an extremist, his book is comprehensive and covers a lot of issues, and overall, offers good insight on usability principles. The other two books offer practical examples of constructing and conducting user tests.

 The Design of Everyday Things - Donald A. Norman
The Design of Everyday Things - Donald A. Norman
Don't Make Me Think : A Common Sense Approach to Web Usability - Steve Krug
Don't Make Me Think : A Common Sense Approach to Web Usability - Steve Krug
 

 The Elements of User Experience: User-Centered Design for the Web - Jesse James Garrett
The Elements of User Experience: User-Centered Design for the Web - Jesse James Garrett